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Published 13:21 23 Oct 2015 BST
Updated 13:26 23 Oct 2015 BST

Saoirse Ronan
Academy Award-nominated actress Saoirse Ronan will be popping into the studio for a chat. The Dubliner will be talking about her highly anticipated film, Brooklyn, which has been creating a bit of Oscar buzz.
Daniel O'Donnell
The Late Late Show has a special theme tonight - country music. So who better to appear then our very own wee Daniel himself. O'Donnell will be performing as well as giving his first major interview since being voted off of Strictly Come Dancing.
https://youtu.be/vGC1BC9tzGM
Clip via BBC Strictly Come Dancing
Big Tom
To continue the Irish country music celebration, Big Tom will make a rare appearance and is set to perform his legendary hit Four Country Roads, along with The Mainliners. Big Tom will joined by young Irish country singers Nathan Carter and Derek Ryan for a big country shindig.
https://youtu.be/hRB9Ae1Ltqs
Clip via SoundOnVision
Christoph Waltz
Joining him will be his co-star and two-time Oscar winner Christoph Waltz, who is making his sofa debut. The German-Austrian appears as Franz Oberhauser in the new flick and we can't wait to see The Django Unchained star's reaction to the red chair stories.
https://youtu.be/H3k1XvAhqUo
Clip via Jimmy Kimmel Live
Naomie Harris
Joining the two lads will be Miss Moneypenny herself, Naomie Harris. The Pirates of the Caribbean actress will reprise her role as Eve Moneypenny in Spectre, having played the same character in Skyfall.
Sam Smith
Finally, no Bond cast would be complete without the official Bond tune, which British superstar Sam Smith will perform live on the show, as the musical guest. Writing's on the Wall has shot up the UK charts since its release, so it will be great to hear live.
https://youtu.be/8jzDnsjYv9A
Clip via SamSmithWorldVEVOExplore more on these topics:

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